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Physical and chemical topics of basic importance in modern fluid mechanics, plasma dynamics, and combustion science: statistical calculations of thermodynamic properties of gases; physical equilibria; quantum mechanical analysis of atomic and molecular structure including rotational and vibrational transitions; atomic-scale collision phenomena and excitation and ionization; emission, absorption, and propagation of radiation. Analyses of major greenhouse gases from point of view of molecular absorption and emission properties; discussion of effect of greenhouse gases concentration and disribution on climate equilibria.